catena-Poly[[[{5,5′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III)]-μ-acetato] methanol monosolvate]
نویسندگان
چکیده
The title Mn(III) compound, {[Mn(C(18)H(18)N(2)O(4))(CH(3)COO)]·CH(3)OH}(n), was synthesized by a reaction between mangan-ese(II) acetate and ethyl-enebis(4-meth-oxy-salicylaldimine). The structure is made up of bis-(4-meth-oxy-salicyldene)ethyl-enediaminatomanganese(III) units bridged by acetate groups, with Mn-N = 1.9786 (9), Mn-O = 1.8784 (10) and Mn-O(acetate) = 2.056 (9) and 2.2571 (9) Å, forming a one dimensional polymer (-Mn-acetate-Mn-acetate-) along [100]. The Mn(III) atom is in a Jahn-Teller-distorted octa-hedral environment with cis angles ranging from 81.87 (4) to 96.53 (4)° and trans angles ranging from 166.11 (3) to 173.93 (3)°. The methanol solvent mol-ecule is hydrogen bonded to the phenolate O atom. In addition to this classical hydrogen bond, there are weak C-H⋯O inter-actions. The structure was determined from a crystal twinned by pseudo-merohedry.
منابع مشابه
Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III)
The title compound, [Mn(C(18)H(18)N(2)O(4))(C(7)H(5)O(3))(H(2)O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxy-salicylaldehyde in presence of manganese(II) 4-hydroxy-benzoate. The Jahn-Teller-distorted manganese(III) centre has an octa-hedral geometry. Extensive O-H⋯O hydrogen-bonding inter-actions generate a two-dimensional sheet structure parallel to (103).
متن کاملDiaqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ2 O,N,N′,O′}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate
In the cation of the title compound, [Mn(C(18)H(18)N(2)O(4))(H(2)O)(2)]ClO(4)·0.5C(12)H(24)O(6)·H(2)O, the Mn(III) ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]di-phenolate ligand, completing a distorted octa-hedral geometry. One O atom of the 18-crown-6-ether is disordered over two ...
متن کاملBis(4-chloropyridine){2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}cobalt(III) perchlorate methanol monosolvate
In the title complex, [Co(C(16)H(14)N(2)O(2))(C(5)H(4)ClN)(2)]ClO(4)·CH(3)OH, the Co(III) ion is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment with the two 4-chloro-pyridine ligands in a trans arrangement.
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-μ-nitrato-dinitratoholmium(III)zinc(II)
In the title heteronuclear Zn(II)-Ho(III) complex (systematic name: {μ-6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κ(4)O(1),O(1'),O(6),O(6'):2κ(4)O(1),N,N',O(1'))-μ-nitrato-1:2κ(2)O:O'-dinitrato-1κ(4)O,O'-holmium(III)zinc(II)), [HoZn(C(18)H(18)N(2)O(4))(NO(3))(3)], with the hexa-dentate Schiff base compartmental ligand N,N'-bis-(3-methoxy-salicyl-idene)ethyl-ened...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-μ-nitrato-dinitratoterbium(III)zinc(II)
In the title heteronuclear Zn(II)-Tb(III) complex (systematic name: {6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-id-yne)]diphenolato-1κ(4)O(6),O(1),O(1'),O(6')}:2κ(4)O(1),N,N',O(1')-μ-nitrato-1:2κ(2)O:O'-dinitrato-1κ(4)O,O'-terbium(III)zinc(II)), [TbZn(C(18)H(18)N(2)O(4))(NO(3))(3)], with the hexa-dentate Schiff base compartmental ligand N,N'-bis-(3-methoxy-salicyl-idene)ethyl-enedi...
متن کامل